Browsing by Author "Papaefstathìou, Giannis S."
Now showing items 1-7 of 7
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A 1-D coordination polymer based on a Mn40 octagonal super-structure
Manoli, Maria; Inglis, R.; Manos, Manolis J.; Papaefstathìou, Giannis S.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2013)A 1-D coordination polymer, constructed using a combination of diols and phenolic oximes, contains a novel [Mn9] sub-unit, a nanosized [Mn40] octagonal super-structure and a [Mn21] repeating unit. © 2013 The Royal Society ...
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Article
A flexible Cd2+ metal organic framework with a unique (3,3,6)-connected topology, unprecedented secondary building units and single crystal to single crystal solvent exchange properties
Kyprianidou, Eleni J.; Papaefstathìou, Giannis S.; Manos, Manolis J.; Tasiopoulos, Anastasios J. (2012)A new flexible Cd2+ metal organic framework (MOF), denoted as UCY-3, which is the second example of a MOF with the ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], is reported. It shows a unique ...
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Article
A highly porous interpenetrated metal-organic framework from the use of a novel nanosized organic linker
Manos, Manolis J.; Markoulides, Marios Savva; Malliakas, C. D.; Papaefstathìou, Giannis S.; Chronakis, Nikos; Kanatzidis, M. G.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2011)The initial use of a novel elongated tricarboxylic acid H3hmpib in metal-organic framework (MOF) chemistry resulted in a [Zn4O(hmpib) 2] MOF (UCY-1) with pyrite topology. The compound displays a remarkably high internal ...
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Article
Insertion of functional groups into a Nd 3+ metal-organic framework via single-crystal-to-single-crystal coordinating solvent exchange
Manos, Manolis J.; Kyprianidou, Eleni J.; Papaefstathìou, Giannis S.; Tasiopoulos, Anastasios J. (2012)Single-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or ...
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A microporous Co2+ metal organic framework with single-crystal to single-crystal transformation properties and high CO2 uptake
Moushi, Eleni E.; Kourtellaris, Andreas; Spanopoulos, Ioannis; Manos, Manolis J.; Papaefstathìou, Giannis S.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2015)The synthesis and characterization of {[Co9(INA)18(H2O)6]·11DMF·15H2O}∞ (Co9-INA·11DMF·15H2O) (INA- = the anion of isonicotinic acid) is reported. It exhibits a rigid 3D-porous structure with a Co9 repeating unit consisting ...
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Article
A microporous Cu2+ MOF based on a pyridyl isophthalic acid Schiff base ligand with high CO2 uptake
Kourtellaris, Andreas; Moushi, Eleni E.; Spanopoulos, Ioannis; Tampaxis, Christos; Charalambopoulou, Georgia Ch; Steriotis, Theodore A.; Papaefstathìou, Giannis S.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2016)A new Cu2+ complex that was isolated from the initial use of 5-((pyridin-4-ylmethylene)amino)isophthalic acid (PEIPH2) in 3d metal-organic framework (MOF) chemistry is reported. Complex {[Cu3(PEIP)2(5-NH2-mBDC)(DMF)]·7DMF}∞ ...
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Article
New Zn 2+ metal organic frameworks with unique network topologies from the combination of trimesic acid and amino-alcohols
Manos, Manolis J.; Moushi, Eleni E.; Papaefstathìou, Giannis S.; Tasiopoulos, Anastasios J. (2012)A series of new Zn 2+-trimesate (btc 3-) metal organic frameworks (MOFs) has been isolated in the presence of various amino-alcohols under solvothermal conditions. Thus, the reaction of ZnCl 2 with trimesic acid (H 3btc) ...